Stereodivergent Synthesis of Aldol Products Using Pseudo-C2 Symmetric N-benzyl-4-(trifluoromethyl)pi...
Stereodivergent Synthesis of Aldol Products Using Pseudo-C2 Symmetric N-benzyl-4-(trifluoromethyl)piperidine-2,6-dione
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Basel: MDPI AG
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English
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Basel: MDPI AG
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The present article describes the successful performance of crossed aldol reactions of the CF3-containing pseudo-C2 symmetric cyclic imide with various aldehydes. The utilization of HMPA as an additive attained the preferential formation of the anti-products in good to excellent yields, which contrasts with our previous method without this additive...
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Stereodivergent Synthesis of Aldol Products Using Pseudo-C2 Symmetric N-benzyl-4-(trifluoromethyl)piperidine-2,6-dione
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TN_cdi_doaj_primary_oai_doaj_org_article_0105f23db7c9438d84a00a6dc7e7e489
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_0105f23db7c9438d84a00a6dc7e7e489
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ISSN
1420-3049
E-ISSN
1420-3049
DOI
10.3390/molecules29215129
