Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH
Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH
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Ding, Jie , Wei, Zhiming , Li, Fuhua , Zhang, Jincheng , Zhang, Qiao , Zhou, Jing , Wang, Weijue , Liu, Yuhang , Zhang, Zhen , Su, Xiaozhi , Yang, Runze , Liu, Wei , Su, Chenliang , Yang, Hong Bin , Huang, Yanqiang , Zhai, Yueming and Liu, Bin
Publisher
London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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In this work, via engineering the conformation of cobalt active center in cobalt phthalocyanine molecular catalyst, the catalytic efficiency of electrochemical carbon monoxide reduction to methanol can be dramatically tuned. Based on a collection of experimental investigations and density functional theory calculations, it reveals that the electron...
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Full title
Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH
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TN_cdi_doaj_primary_oai_doaj_org_article_0a2a504caa614ca8a948ce31524b7fcc
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_0a2a504caa614ca8a948ce31524b7fcc
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-023-42307-1