Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion fr...
Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Metalloenzymes preorganize the reaction environment to steer substrate(s) along the required reaction coordinate. Here, we show that phosphine ligands selectively facilitate protonation of binuclear silver hydride cations, [LAg
2
(H)]
+
by optimizing the geometry of the active site. This is a key step in the selective, catalysed extrusi...
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Full title
Ligand-induced substrate steering and reshaping of [Ag2(H)]+ scaffold for selective CO2 extrusion from formic acid
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TN_cdi_doaj_primary_oai_doaj_org_article_5c9942ddd8b84c90bbfe868edef555cf
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_5c9942ddd8b84c90bbfe868edef555cf
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/ncomms11746
