Organocatalytic asymmetric synthesis of Si-stereogenic silacycles
Organocatalytic asymmetric synthesis of Si-stereogenic silacycles
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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A strong and confined Brønsted acid catalyzed enantioselective cyclization of bis(methallyl)silanes provides enantioenriched
Si
-stereogenic silacycles. High enantioselectivities of up to 96.5:3.5 er were obtained for a range of bis(methallyl)silanes. NMR and ESI-MS studies reveal that the formation of a covalent adduct irreversibly inhibits...
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Organocatalytic asymmetric synthesis of Si-stereogenic silacycles
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TN_cdi_doaj_primary_oai_doaj_org_article_607f358b5c0b4054b83dc90b8ad04ec4
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_607f358b5c0b4054b83dc90b8ad04ec4
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-024-49988-2
