RuO4-mediated oxidation of secondary amines: Part 1. Are hydroxylamines main intermediates?
RuO4-mediated oxidation of secondary amines: Part 1. Are hydroxylamines main intermediates?
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Serbian Chemical Society
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Language
English
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Serbian Chemical Society
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Contents
The RuO4-catalyzed oxidation of secondary amines Bn-NH-CH2R (1a-b; R=H, Me)
gave mainly amides, but minute amounts of nitrones PhCH=N(O)-CH2R (9a-b) and
traces of Bn-N(OH)-CH2R (R=H, 4a) were also detected. In the presence of
cyanide, up to 22 reaction products were identified, but mainly
?-aminonitriles. Comparison of the oxidation pro...
Alternative Titles
Full title
RuO4-mediated oxidation of secondary amines: Part 1. Are hydroxylamines main intermediates?
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TN_cdi_doaj_primary_oai_doaj_org_article_61b4196d40ed4597a6f124c40c1c6735
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_61b4196d40ed4597a6f124c40c1c6735
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ISSN
0352-5139
E-ISSN
1820-7421
DOI
10.2298/JSC151215029F
