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Kinetics, Mechanism and Theoretical Studies of Norbornene-Ethylene Alternating Copolymerization Cata...

Kinetics, Mechanism and Theoretical Studies of Norbornene-Ethylene Alternating Copolymerization Cata...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_881cae6d4b3c4269b562745db20f6887

Kinetics, Mechanism and Theoretical Studies of Norbornene-Ethylene Alternating Copolymerization Catalyzed by Organopalladium(II) Complexes Bearing Hemilabile α-Amino-pyridine

About this item

Full title

Kinetics, Mechanism and Theoretical Studies of Norbornene-Ethylene Alternating Copolymerization Catalyzed by Organopalladium(II) Complexes Bearing Hemilabile α-Amino-pyridine

Publisher

Switzerland: MDPI AG

Journal title

Molecules (Basel, Switzerland), 2017-06, Vol.22 (7), p.1095

Language

English

Formats

Publication information

Publisher

Switzerland: MDPI AG

More information

Scope and Contents

Contents

Cationic methylpalladium complexes bearing hemilabile bidentate α-amino-pyridines can serve as effective precursors for catalytic alternating copolymerization of norbornene (N) and ethylene (E), under mild conditions. The norbornyl palladium complexes in the formula of {[RHNCH₂(
-C₆H₄N)]Pd(C₇H
Me)(NCMe)}(BF₄) (R =
Pr (
),
Bu (
),...

Alternative Titles

Full title

Kinetics, Mechanism and Theoretical Studies of Norbornene-Ethylene Alternating Copolymerization Catalyzed by Organopalladium(II) Complexes Bearing Hemilabile α-Amino-pyridine

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_doaj_primary_oai_doaj_org_article_881cae6d4b3c4269b562745db20f6887

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_881cae6d4b3c4269b562745db20f6887

Other Identifiers

ISSN

1420-3049

E-ISSN

1420-3049

DOI

10.3390/molecules22071095

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