Skeletal rearrangement of 6,8-dioxabicyclo[3.2.1]octan-4-ols promoted by thionyl chloride or Appel c...
Skeletal rearrangement of 6,8-dioxabicyclo[3.2.1]octan-4-ols promoted by thionyl chloride or Appel conditions
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Publisher
Germany: Beilstein-Institut
Journal title
Language
English
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Publisher
Germany: Beilstein-Institut
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Contents
A skeletal rearrangement of a series of 6,8-dioxabicyclo[3.2.1]octan-4-ols has been developed using SOCl
2
in the presence of pyridine. An oxygen migration from C5 to C4 was observed when the C4 alcohols were treated with SOCl
2
/pyridine, giving a 2-chloro-3,8-dioxabicyclo[3.2.1]octane ring-system via the chlorosulfite intermediate. An...
Alternative Titles
Full title
Skeletal rearrangement of 6,8-dioxabicyclo[3.2.1]octan-4-ols promoted by thionyl chloride or Appel conditions
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Record Identifier
TN_cdi_doaj_primary_oai_doaj_org_article_89ca432e079b44a78f7cbd7e2408b0a3
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_89ca432e079b44a78f7cbd7e2408b0a3
Other Identifiers
ISSN
1860-5397
E-ISSN
1860-5397
DOI
10.3762/bjoc.20.74
