Ag3PO4 enables the generation of long-lived radical cations for visible light-driven [2 + 2] and [4...
Ag3PO4 enables the generation of long-lived radical cations for visible light-driven [2 + 2] and [4 + 2] pericyclic reactions
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Author / Creator
Guo, Lirong , Chu, Rongchen , Hao, Xinyu , Lei, Yu , Li, Haibin , Ma, Dongge , Wang, Guo , Tung, Chen-Ho and Wang, Yifeng
Publisher
London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Photocatalytic redox reactions are important for synthesizing fine chemicals from olefins, but the limited lifetime of radical cation intermediates severely restricts semiconductor photocatalysis efficiency. Here, we report that Ag
3
PO
4
can efficiently catalyze intramolecular and intermolecular [2 + 2] and Diels-Alder cycloadditions u...
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Full title
Ag3PO4 enables the generation of long-lived radical cations for visible light-driven [2 + 2] and [4 + 2] pericyclic reactions
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TN_cdi_doaj_primary_oai_doaj_org_article_9bafe9c2d0c74b93865d59df67e5a4ef
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_9bafe9c2d0c74b93865d59df67e5a4ef
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-024-45217-y