Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
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Publisher
Germany: Beilstein-Institut zur Föerderung der Chemischen Wissenschaften
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Language
English
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Publisher
Germany: Beilstein-Institut zur Föerderung der Chemischen Wissenschaften
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Contents
A copper-based photocatalyst, Cu(tmp)(BINAP)BF
, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protoco...
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Full title
Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow
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TN_cdi_doaj_primary_oai_doaj_org_article_b0735e1c41054d35b697a20b6fafd15a
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_b0735e1c41054d35b697a20b6fafd15a
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ISSN
1860-5397,2195-951X
E-ISSN
1860-5397
DOI
10.3762/bjoc.14.251