Application of chiral 2-isoxazoline for the synthesis of syn -1,3-diol analogs
Application of chiral 2-isoxazoline for the synthesis of syn -1,3-diol analogs
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Author / Creator
Publisher
Germany: Beilstein-Institut zur Föerderung der Chemischen Wissenschaften
Journal title
Language
English
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Publisher
Germany: Beilstein-Institut zur Föerderung der Chemischen Wissenschaften
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Scope and Contents
Contents
The asymmetric cycloaddition of TIPS nitronate catalyzed by “Cu(II)-bisoxazoline” gave the 2-isoxazoline product in 95% yield, which was converted into
tert
-butyl (3
S
,5
R
)-6-hydroxy-3,5-
O
-isopropylidene-3,5-dihydroxyhexanoate in 14 steps through a β-hydroxy ketone.
Alternative Titles
Full title
Application of chiral 2-isoxazoline for the synthesis of syn -1,3-diol analogs
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Author / Creator
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Record Identifier
TN_cdi_doaj_primary_oai_doaj_org_article_c191da1db4a742c29b24f445a0283e5c
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_c191da1db4a742c29b24f445a0283e5c
Other Identifiers
ISSN
1860-5397,2195-951X
E-ISSN
1860-5397
DOI
10.3762/bjoc.15.179
