An Innovative Structural Rearrangement in Imine Palladacycle Metaloligand Chemistry: From Single-Nuc...
An Innovative Structural Rearrangement in Imine Palladacycle Metaloligand Chemistry: From Single-Nuclear to Double-Nuclear Pseudo-Pentacoordinated Complexes
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Switzerland: MDPI AG
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English
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Switzerland: MDPI AG
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Treatment of the double nuclear complex 1a, di-μ-cloro-bis[N-(4-formylbenzylidene)cyclohexylaminato-C6, N]dipalladium, with Ph2PCH2CH2)2PPh (triphos) and NH4PF6 gave the single nuclear species 2a, 1-N-(cyclohexylamine)-4-N-(formyl)palladium(triphos)(hexafluorophasphate). Reaction of 2a with Ph2PCH2CH2NH2 in refluxing chloroform via a condensation r...
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An Innovative Structural Rearrangement in Imine Palladacycle Metaloligand Chemistry: From Single-Nuclear to Double-Nuclear Pseudo-Pentacoordinated Complexes
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TN_cdi_doaj_primary_oai_doaj_org_article_d3792f58feb64d43898fa3ec33cf68ea
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_d3792f58feb64d43898fa3ec33cf68ea
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ISSN
1420-3049
E-ISSN
1420-3049
DOI
10.3390/molecules28052328
