Observation of a re-entrant phase transition in the molecular complex tris(μ 2 -3,5-diiso-propyl-1,2...
Observation of a re-entrant phase transition in the molecular complex tris(μ 2 -3,5-diiso-propyl-1,2,4-triazolato-κ 2 N 1 : N 2 )trigold(I) under high pressure
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Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States) , Woodall, Christopher H , Christensen, Jeppe , Skelton, Jonathan M , Hatcher, Lauren E , Parlett, Andrew , Raithby, Paul R , Walsh, Aron , Parker, Stephen C , Beavers, Christine M , Teat, Simon J , Intissar, Mourad , Reber, Christian and Allan, David R
Publisher
England: International Union of Crystallography
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Language
English
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Publisher
England: International Union of Crystallography
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Contents
We report a molecular crystal that exhibits four successive phase transitions under hydro-static pressure, driven by aurophilic interactions, with the ground-state structure re-emerging at high pressure. The effect of pressure on two polytypes of tris(μ
-3,5-diiso-propyl-1,2,4-triazolato-κ
:
)trigold(I) (denoted Form-I and Form-II) has bee...
Alternative Titles
Full title
Observation of a re-entrant phase transition in the molecular complex tris(μ 2 -3,5-diiso-propyl-1,2,4-triazolato-κ 2 N 1 : N 2 )trigold(I) under high pressure
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TN_cdi_doaj_primary_oai_doaj_org_article_e438a285aa4e4d7f9ca590d04a54f295
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_e438a285aa4e4d7f9ca590d04a54f295
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ISSN
2052-2525
E-ISSN
2052-2525
DOI
10.1107/S2052252516013129
