Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Acid catalysis by hydronium ions is ubiquitous in aqueous-phase organic reactions. Here we show that hydronium ion catalysis, exemplified by intramolecular dehydration of cyclohexanol, is markedly influenced by steric constraints, yielding turnover rates that increase by up to two orders of magnitude in tight confines relative to an aqueous solutio...
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Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
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TN_cdi_doaj_primary_oai_doaj_org_article_ee88384707244e91aced7e3a4cf5209f
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_ee88384707244e91aced7e3a4cf5209f
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/ncomms15442
