RuO4-mediated oxidation of secondary amines 2. imines as main reaction intermediates
RuO4-mediated oxidation of secondary amines 2. imines as main reaction intermediates
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Belgrade: Journal of the Serbian Chemical Society
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English
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Belgrade: Journal of the Serbian Chemical Society
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Oxidation by RuO4 (generated in situ from RuO2 and NaIO4) of secondary amines like Bn-NH-CH2R (1; R=H, Me) gave complex reaction mixtures, but mainly amides. In the presence of cyanide, the leading products were α-aminonitriles. Comparison of the oxidation products of 1 with those from the corresponding imines PhCH=N-CH2R and Bn-N=CH-R showed that...
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RuO4-mediated oxidation of secondary amines 2. imines as main reaction intermediates
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TN_cdi_doaj_primary_oai_doaj_org_article_f58fa33e824e4d16a8505a2155dfe577
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_f58fa33e824e4d16a8505a2155dfe577
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ISSN
0352-5139
E-ISSN
1820-7421
DOI
10.2298/JSC160914055F
