One-electron oxidation of an oxoiron(IV) complex to form an [O═Feⱽ═NR]⁺ center
One-electron oxidation of an oxoiron(IV) complex to form an [O═Feⱽ═NR]⁺ center
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Publisher
United States: National Academy of Sciences
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Language
English
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United States: National Academy of Sciences
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Oxoiron(V) species are postulated to be involved in the mechanisms of the arene cis -dihydroxylating Rieske dioxygenases and of bioinspired nonheme iron catalysts for alkane hydroxylation, olefin cis -dihydroxylation, and water oxidation. In an effort to obtain a synthetic oxoiron(V) complex, we report herein the one-electron oxidation of the S = 1...
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Full title
One-electron oxidation of an oxoiron(IV) complex to form an [O═Feⱽ═NR]⁺ center
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TN_cdi_fao_agris_US201600129140
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_fao_agris_US201600129140
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ISSN
0027-8424
E-ISSN
1091-6490
DOI
10.1073/pnas.1206457109
