Log in to save to my catalogue

Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3...

Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_hal_primary_oai_HAL_hal_03616827v1

Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3-mesityl-imidazolium iodide: redox potential and substituent effects

About this item

Full title

Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3-mesityl-imidazolium iodide: redox potential and substituent effects

Publisher

Chemical Society of Ethiopia

Journal title

Bulletin of the Chemical Society of Ethiopia, 2021-01, Vol.34 (3), p.605-612

Language

English

Formats

Publication information

Publisher

Chemical Society of Ethiopia

More information

Scope and Contents

Contents

The electrochemical behavior of 1-ferrocenylmethyl-3-(methyl)-imidazolium iodide (or mesityl) imidazolium was studied by cyclic voltammetry at glassy carbon electrode in midiums organic to determine the influences of electronic imidazolium group on the ferrocene. The experimental results indicated that the redox reaction was reversible. Mass transport towards the electrode is a simple diffusion process and the diffusion coefficient (D) for redox couple has been also calculated and we have evaluated the heterogeneous charge transfer rate constant (K0).
                   
KEY WORDS: Electrochemical behaviour, Cyclic voltammetry, Imidazolium salts, Diffusion coefficient
 
Bull. Chem. Soc. Ethiop. 2020, 34(3), 605-612.
DOI: https://dx.doi.org/10.4314/bcse.v34i3.15...

Alternative Titles

Full title

Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3-mesityl-imidazolium iodide: redox potential and substituent effects

Authors, Artists and Contributors

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_hal_primary_oai_HAL_hal_03616827v1

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_hal_primary_oai_HAL_hal_03616827v1

Other Identifiers

ISSN

1011-3924

E-ISSN

1726-801X

DOI

10.4314/bcse.v34i3.15

How to access this item