High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II
High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II
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United States: National Academy of Sciences
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Language
English
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Publisher
United States: National Academy of Sciences
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Contents
The structural and electronic properties of a series of manganese complexes with terminal oxido ligands are described. The complexes span three different oxidation states at the manganese center (III–V), have similar molecular structures, and contain intramolecular hydrogen-bonding networks surrounding the Mn–oxo unit. Structural studies using X-ra...
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Full title
High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II
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TN_cdi_osti_scitechconnect_1235170
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_osti_scitechconnect_1235170
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ISSN
0027-8424
E-ISSN
1091-6490
DOI
10.1073/pnas.1422800112
