synthetic precedent for the [FeIV₂(μ-O)₂] diamond core proposed for methane monooxygenase intermedia...
synthetic precedent for the [FeIV₂(μ-O)₂] diamond core proposed for methane monooxygenase intermediate Q
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Publisher
United States: National Academy of Sciences
Journal title
Language
English
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Publication information
Publisher
United States: National Academy of Sciences
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Scope and Contents
Contents
Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [FeIV₂(μ-O)₂] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc⁺/⁰) has been performed in MeCN at -40°C on a valence-delocalized [FeIIIFeIV(μ-O)₂(Lb)₂]³⁺ complex (1b) (E₁/₂ = 760 mV...
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Full title
synthetic precedent for the [FeIV₂(μ-O)₂] diamond core proposed for methane monooxygenase intermediate Q
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Record Identifier
TN_cdi_pnas_primary_104_52_20713
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pnas_primary_104_52_20713
Other Identifiers
ISSN
0027-8424
E-ISSN
1091-6490
DOI
10.1073/pnas.0708516105
