In situ characterization of cofacial Co(IV) centers in Co^sub 4^O^sub 4^ cubane: Modeling the high-v...
In situ characterization of cofacial Co(IV) centers in Co^sub 4^O^sub 4^ cubane: Modeling the high-valent active site in oxygen-evolving catalysts
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Washington: National Academy of Sciences
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English
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Washington: National Academy of Sciences
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The Co^sub 4^O^sub 4^ cubane is a representative structural model of oxidic cobalt oxygen-evolving catalysts (Co-OECs). The Co-OECs are active when residing at two oxidation levels above an all-Co(III) resting state. This doubly oxidized Co(IV)2 state may be captured in a Co(III)^sub 2^(IV)^sub 2^ cubane. We demonstrate that the Co(III)^sub 2^(IV)^...
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In situ characterization of cofacial Co(IV) centers in Co^sub 4^O^sub 4^ cubane: Modeling the high-valent active site in oxygen-evolving catalysts
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TN_cdi_proquest_journals_1896938389
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_1896938389
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0027-8424
E-ISSN
1091-6490
