RuO4-Mediated oxidation of secondary amines. 1. Are hydroxylamines main intermediates? [Supplementar...
RuO4-Mediated oxidation of secondary amines. 1. Are hydroxylamines main intermediates? [Supplementary Material]
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Belgrade: Journal of the Serbian Chemical Society
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English
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Belgrade: Journal of the Serbian Chemical Society
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The RuO4-catalyzed oxidation of secondary amines Bn-NH-CH2R (1a-b; R=H, Me) gave mainly amides, but minute amounts of nitrones PhCH=N(O)-CH2R (9a-b) and traces of Bn-N(OH)-CH2R (R=H, 4a) were also detected. In the presence of cyanide, up to 22 reaction products were identified, but mainly α-aminonitriles. Comparison of the oxidation products of 1a-...
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RuO4-Mediated oxidation of secondary amines. 1. Are hydroxylamines main intermediates? [Supplementary Material]
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TN_cdi_proquest_journals_1962305051
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_1962305051
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ISSN
0352-5139
E-ISSN
1820-7421
DOI
10.2298/JSC151215029F
