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Doming Modes and Dynamics of Model Heme Compounds

Doming Modes and Dynamics of Model Heme Compounds

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_201378283

Doming Modes and Dynamics of Model Heme Compounds

About this item

Full title

Doming Modes and Dynamics of Model Heme Compounds

Publisher

United States: National Academy of Sciences

Journal title

Proceedings of the National Academy of Sciences - PNAS, 2002-10, Vol.99 (20), p.12526-12530

Language

English

Formats

Publication information

Publisher

United States: National Academy of Sciences

More information

Scope and Contents

Contents

Synchrotron far-IR spectroscopy and density-functional calculations are used to characterize the low-frequency dynamics of model heme FeCO compounds. The "doming" vibrational mode in which the iron atom moves out of the porphyrin plane while the periphery of this ring moves in the opposite direction determines the reactivity of oxygen with this typ...

Alternative Titles

Full title

Doming Modes and Dynamics of Model Heme Compounds

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_journals_201378283

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_201378283

Other Identifiers

ISSN

0027-8424

E-ISSN

1091-6490

DOI

10.1073/pnas.152464699

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