Doming Modes and Dynamics of Model Heme Compounds
Doming Modes and Dynamics of Model Heme Compounds
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United States: National Academy of Sciences
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Language
English
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United States: National Academy of Sciences
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Synchrotron far-IR spectroscopy and density-functional calculations are used to characterize the low-frequency dynamics of model heme FeCO compounds. The "doming" vibrational mode in which the iron atom moves out of the porphyrin plane while the periphery of this ring moves in the opposite direction determines the reactivity of oxygen with this typ...
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Doming Modes and Dynamics of Model Heme Compounds
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TN_cdi_proquest_journals_201378283
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_201378283
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ISSN
0027-8424
E-ISSN
1091-6490
DOI
10.1073/pnas.152464699