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Intramolecular [4 + 3] cycloadditions - Stereochemical issues in the cycloaddition reactions of cycl...

Intramolecular [4 + 3] cycloadditions - Stereochemical issues in the cycloaddition reactions of cycl...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_218667441

Intramolecular [4 + 3] cycloadditions - Stereochemical issues in the cycloaddition reactions of cyclopentenyl cations - A synthesis of (+)-dactylol1

About this item

Full title

Intramolecular [4 + 3] cycloadditions - Stereochemical issues in the cycloaddition reactions of cyclopentenyl cations - A synthesis of (+)-dactylol1

Publisher

Ottawa: Canadian Science Publishing NRC Research Press

Journal title

Canadian journal of chemistry, 2006-10, Vol.84 (10), p.1456

Language

English

Formats

Publication information

Publisher

Ottawa: Canadian Science Publishing NRC Research Press

More information

Scope and Contents

Contents

Five cyclopentanones were prepared for the purpose of examining the effects of stereogenic centers on the course of the intramolecular [4 + 3] cycloaddition reactions of cyclopentenyl cations. One substrate reacted with very high levels of diastereoselectivity and was converted to (+)-dactylol. The cyclopentenone without stereogenic centers on the...

Alternative Titles

Full title

Intramolecular [4 + 3] cycloadditions - Stereochemical issues in the cycloaddition reactions of cyclopentenyl cations - A synthesis of (+)-dactylol1

Authors, Artists and Contributors

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_journals_218667441

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_218667441

Other Identifiers

ISSN

0008-4042

E-ISSN

1480-3291

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