Thermal rearrangements during liquid–vapor phase pyrolysis polycondensation of polysilane to high-fu...
Thermal rearrangements during liquid–vapor phase pyrolysis polycondensation of polysilane to high-functional polycarbosilane: spectral and thermal studies
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Cham: Springer International Publishing
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English
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Cham: Springer International Publishing
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Thermally induced Kumada rearrangement of –Si–Si– linear chains in polysilanes to –Si–C– chain was conducted in the liquid–vapor phase, followed by isothermal treatments at 410, 460 °C and pressure of 15 kgf cm
−2
leading to polycarbosilane(PCS) with higher silane (–Si–H) content in the range 0.46–0.58 mass%. Molecular and thermal changes dur...
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Full title
Thermal rearrangements during liquid–vapor phase pyrolysis polycondensation of polysilane to high-functional polycarbosilane: spectral and thermal studies
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TN_cdi_proquest_journals_2618938962
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2618938962
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ISSN
1388-6150
E-ISSN
1588-2926
DOI
10.1007/s10973-020-10459-7
