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An efficient catalytic system for the synthesis of glycerol carbonate by oxidative carbonylation of...

An efficient catalytic system for the synthesis of glycerol carbonate by oxidative carbonylation of...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2918607727

An efficient catalytic system for the synthesis of glycerol carbonate by oxidative carbonylation of glycerol

About this item

Full title

An efficient catalytic system for the synthesis of glycerol carbonate by oxidative carbonylation of glycerol

Publisher

Berlin/Heidelberg: Springer Berlin Heidelberg

Journal title

Science China. Chemistry, 2013-10, Vol.56 (10), p.1455-1462

Language

English

Formats

Publication information

Publisher

Berlin/Heidelberg: Springer Berlin Heidelberg

More information

Scope and Contents

Contents

Glycerol carbonate was synthesized by the oxidative carbonylation of glycerol catalyzed by the commercial Pd/C with the aid of NaI. High conversion of glycerol (82.2%), selectivity to glycerol carbonate (〉99%), and TOF (900 h-1) were obtained under the conditions of 5 MPa (Pco:Po2 = 2:1), 140 C, 2 h. The highly active palladium species were generat...

Alternative Titles

Full title

An efficient catalytic system for the synthesis of glycerol carbonate by oxidative carbonylation of glycerol

Authors, Artists and Contributors

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_journals_2918607727

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2918607727

Other Identifiers

ISSN

1674-7291

E-ISSN

1869-1870

DOI

10.1007/s11426-013-4918-5

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