Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
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Author / Creator
Chen, Yu , Au, Yik Ki , Quan, Yangjian and Xie, Zuowei
Publisher
Beijing: Science China Press
Journal title
Language
English
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Publisher
Beijing: Science China Press
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Scope and Contents
Contents
Base metal catalyzed regioselective cage B–H functionalization has been achieved. Under the assistance of a bidentate directing group, Cu-catalyzed [4+2] annulation of carboranyl amides with internal alkynes affords unprecedented C,B-substituted carborane-fused-pyridone derivatives, whereas the use of terminal alkynes leads to B–H/C(sp)–H dehydroco...
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Full title
Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
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Record Identifier
TN_cdi_proquest_journals_2918618554
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2918618554
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ISSN
1674-7291
E-ISSN
1869-1870
DOI
10.1007/s11426-018-9388-3