Synthesis and Structure of Polyhydrido Copper Nanocluster [Cu14H10(PPh3)8(SPhMe2)3]+: Symmetry-Break...
Synthesis and Structure of Polyhydrido Copper Nanocluster [Cu14H10(PPh3)8(SPhMe2)3]+: Symmetry-Breaking by Thiolate Ligands to form Racemic Pairs of Chiral Clusters in Solid-State
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Full title
Author / Creator
Zeng, Shuhuan , Ge, Xin , Deng, Hongwen , Hao, Shuwei , Zhang, Zhiye , Teo, Boon K. and Sun, Cunfa
Publisher
New York: Springer US
Journal title
Language
English
Formats
Publication information
Publisher
New York: Springer US
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More information
Scope and Contents
Contents
A polyhydrido copper nanocluster, [Cu
14
H
10
(PPh
3
)
8
(SR)
3
]
+
(HSR = 2,4-dimethylbenzenethiol), adopting a distorted
fcc
structure, is reported. One cube-vertex copper atom, coordinated by the three thiolate ligands and a PPh
3
, protrudes outwards from the
fcc
metal framework. The twistin...
Alternative Titles
Full title
Synthesis and Structure of Polyhydrido Copper Nanocluster [Cu14H10(PPh3)8(SPhMe2)3]+: Symmetry-Breaking by Thiolate Ligands to form Racemic Pairs of Chiral Clusters in Solid-State
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Author / Creator
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Record Identifier
TN_cdi_proquest_journals_2921360258
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_2921360258
Other Identifiers
ISSN
1040-7278
E-ISSN
1572-8862
DOI
10.1007/s10876-023-02469-w
