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Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_867893033

Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

About this item

Full title

Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

Publisher

London: Nature Publishing Group UK

Journal title

Nature chemistry, 2010-06, Vol.2 (6), p.478-483

Language

English

Formats

Publication information

Publisher

London: Nature Publishing Group UK

More information

Scope and Contents

Contents

Direct functionalization of alkanes by oxidation of C–H bonds to form alcohols under mild conditions is a challenge for synthetic chemistry. Most alkanes contain a large number of C–H bonds that present difficulties for selectivity, and the oxidants employed often result in overoxidation. Here we describe a divanadium-substituted phosphotungstate t...

Alternative Titles

Full title

Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_journals_867893033

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_867893033

Other Identifiers

ISSN

1755-4330

E-ISSN

1755-4349

DOI

10.1038/nchem.648

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