Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate
Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Direct functionalization of alkanes by oxidation of C–H bonds to form alcohols under mild conditions is a challenge for synthetic chemistry. Most alkanes contain a large number of C–H bonds that present difficulties for selectivity, and the oxidants employed often result in overoxidation. Here we describe a divanadium-substituted phosphotungstate t...
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Efficient stereo- and regioselective hydroxylation of alkanes catalysed by a bulky polyoxometalate
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TN_cdi_proquest_journals_867893033
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_journals_867893033
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1755-4330
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1755-4349
DOI
10.1038/nchem.648