Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems
Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems
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United States: National Academy of Sciences
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English
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United States: National Academy of Sciences
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Molecular dynamics simulations show that the desolvation rates of isotopes of Li ⁺, K ⁺, Rb ⁺, Ca ²⁺, Sr ²⁺, and Ba ²⁺ may have a relatively strong dependence on the metal cation mass. This inference is based on the observation that the exchange rate constant, k wₑₓ, for water molecules in the first hydration shell follows an inverse power-law mass...
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Full title
Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems
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TN_cdi_proquest_miscellaneous_1171860219
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_1171860219
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ISSN
0027-8424
E-ISSN
1091-6490
DOI
10.1073/pnas.1208184109
