Alkane desaturation by concerted double hydrogen atom transfer to benzyne
Alkane desaturation by concerted double hydrogen atom transfer to benzyne
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Benzynes are capable of concerted removal of two vicinal hydrogen atoms from a hydrocarbon, a discovery enabled by the thermal generation of reactive benzyne intermediates through the hexadehydro-Diels–Alder cycloisomerization reaction of triyne substrates.
A new route for C–H activation
This paper reports a new route for the dehydrogenation...
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Alkane desaturation by concerted double hydrogen atom transfer to benzyne
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TN_cdi_proquest_miscellaneous_1437581010
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_1437581010
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ISSN
0028-0836
E-ISSN
1476-4687
DOI
10.1038/nature12492