Amine(imine) diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines
Amine(imine) diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines
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Washington, DC: American Association for the Advancement of Science
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English
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Washington, DC: American Association for the Advancement of Science
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Contents
A rational approach is needed to design hydrogénation catalysts that make use of Earth-abundant elements to replace the rare elements such as ruthenium, rhodium, and palladium that are traditionally used. Here, we validate a prior mechanistic hypothesis that partially saturated amine(imine) diphosphine ligands (P-NH-N-P) activate iron to catalyze t...
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Amine(imine) diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines
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TN_cdi_proquest_miscellaneous_1559693172
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_1559693172
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ISSN
0036-8075
E-ISSN
1095-9203
DOI
10.1126/science.1244466
