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Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_1904251179

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

About this item

Full title

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

Publisher

Washington: American Association for the Advancement of Science

Journal title

Science (American Association for the Advancement of Science), 2014-11, Vol.346 (6211), p.834-837

Language

English

Formats

Publication information

Publisher

Washington: American Association for the Advancement of Science

More information

Scope and Contents

Contents

The regioselectivity of deprotonation reactions between arene substrates and basic metalating agents is usually governed by the electronic and/or coordinative characteristics of a directing group attached to the benzene ring. Generally, the reaction takes place in the ortho position, adjacent to the substituent. Here, we introduce a protocol by whi...

Alternative Titles

Full title

Directed ortho-meta′- and meta-meta′-dimetalations: A template base approach to deprotonation

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_miscellaneous_1904251179

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_1904251179

Other Identifiers

ISSN

0036-8075

E-ISSN

1095-9203

DOI

10.1126/science.1259662

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