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Confirmation of the absolute configuration of Stachybotrin C using single-crystal X-ray diffraction...

Confirmation of the absolute configuration of Stachybotrin C using single-crystal X-ray diffraction...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_2015837112

Confirmation of the absolute configuration of Stachybotrin C using single-crystal X-ray diffraction analysis of its 4-bromobenzyl ether derivative

About this item

Full title

Confirmation of the absolute configuration of Stachybotrin C using single-crystal X-ray diffraction analysis of its 4-bromobenzyl ether derivative

Publisher

London: Nature Publishing Group UK

Journal title

Journal of antibiotics, 2018-06, Vol.71 (6), p.584-591

Language

English

Formats

Publication information

Publisher

London: Nature Publishing Group UK

More information

Scope and Contents

Contents

The absolute configuration of Stachybotrin C was confirmed in this study. After synthesizing the dimethyl ethers of Stachybotrin C, the C-8 epimer was analyzed by 1D NOESY. However, the stereochemistry determination was difficult through the NOE correlations. Instead, the di(4-bromobenzyl) ether of Stachybotrin C was derived and used for X-ray diff...

Alternative Titles

Full title

Confirmation of the absolute configuration of Stachybotrin C using single-crystal X-ray diffraction analysis of its 4-bromobenzyl ether derivative

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_proquest_miscellaneous_2015837112

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_2015837112

Other Identifiers

ISSN

0021-8820

E-ISSN

1881-1469

DOI

10.1038/s41429-018-0042-2

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