A light-driven enzymatic enantioselective radical acylation
A light-driven enzymatic enantioselective radical acylation
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Author / Creator
Xu, Yuanyuan , Chen, Hongwei , Yu, Lu , Peng, Xichao , Zhang, Jiawei , Xing, Zhongqiu , Bao, Yuyan , Liu, Aokun , Zhao, Yue , Tian, Changlin , Liang, Yong and Huang, Xiaoqiang
Publisher
London: Nature Publishing Group UK
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Language
English
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Publisher
London: Nature Publishing Group UK
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Contents
Enzymes are recognized as exceptional catalysts for achieving high stereoselectivities
1
–
3
, but their ability to control the reactivity and stereoinduction of free radicals lags behind that of chemical catalysts
4
. Thiamine diphosphate (ThDP)-dependent enzymes
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are well-characterized systems that inspired the developmen...
Alternative Titles
Full title
A light-driven enzymatic enantioselective radical acylation
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Record Identifier
TN_cdi_proquest_miscellaneous_2903860329
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_2903860329
Other Identifiers
ISSN
0028-0836
E-ISSN
1476-4687
DOI
10.1038/s41586-023-06822-x