A Carbon-Free Sandwich Complex [(P5)2Ti]2
A Carbon-Free Sandwich Complex [(P5)2Ti]2
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Publisher
Washington, DC: American Society for the Advancement of Science
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Language
English
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Publisher
Washington, DC: American Society for the Advancement of Science
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Scope and Contents
Contents
Reactions of highly reduced titanium complexes with white phosphorus, P4, at or below 25°C yielded brown to deep red-brown salts of the first entirely inorganic metallocene, [(η5-P5)2Ti]2-(1). Like ferrocene and other carbon-based metallocenes, the structure of 1 has parallel and planar five-membered rings symmetrically positioned about the central...
Alternative Titles
Full title
A Carbon-Free Sandwich Complex [(P5)2Ti]2
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Record Identifier
TN_cdi_proquest_miscellaneous_71427394
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_71427394
Other Identifiers
ISSN
0036-8075
E-ISSN
1095-9203
DOI
10.1126/science.1067325
