Computational evidence that hyperconjugative interactions are not responsible for the anomeric effec...
Computational evidence that hyperconjugative interactions are not responsible for the anomeric effect
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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The ‘anomeric effect’ is the thermodynamic preference for polar substituents to occupy the axial position in the chair conformation of various heterocycles. The most common explanation given for this effect at present is hyperconjugation from the lone pairs on the ring heteroatom to the antibonding orbital between the anomeric carbon and its linkin...
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Computational evidence that hyperconjugative interactions are not responsible for the anomeric effect
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TN_cdi_proquest_miscellaneous_734007484
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_734007484
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1755-4330
E-ISSN
1755-4349
DOI
10.1038/nchem.721
