A coordination chemistry dichotomy for icosahedral carborane-based ligands
A coordination chemistry dichotomy for icosahedral carborane-based ligands
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Although the majority of ligands in modern chemistry take advantage of carbon-based substituent effects to tune the sterics and electronics of coordinating moieties, we describe here how icosahedral carboranes—boron-rich clusters—can influence metal–ligand interactions. Using a series of phosphine–thioether chelating ligands featuring meta- or orth...
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Full title
A coordination chemistry dichotomy for icosahedral carborane-based ligands
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TN_cdi_proquest_miscellaneous_878822441
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_878822441
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ISSN
1755-4330
E-ISSN
1755-4349
DOI
10.1038/nchem.1088
