Steric Control of the Reaction of CH Stretch-Excited CHD₃ with Chlorine Atom
Steric Control of the Reaction of CH Stretch-Excited CHD₃ with Chlorine Atom
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Washington, DC: American Association for the Advancement of Science
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English
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Washington, DC: American Association for the Advancement of Science
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Contents
Exciting the CH-stretching mode of CHD₃ (where D is deuterium) is known to promote the C-H bond's reactivity toward chlorine (Cl) atom. Conventional wisdom ascribes the vibrational-rate enhancement to a widening of the cone of acceptance (i.e., the collective Cl approach trajectories that lead to reaction). A previous study of this reaction indicat...
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Full title
Steric Control of the Reaction of CH Stretch-Excited CHD₃ with Chlorine Atom
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TN_cdi_proquest_miscellaneous_907933463
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_907933463
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ISSN
0036-8075
E-ISSN
1095-9203
DOI
10.1126/science.1199771
