No Straight Path: Roaming in Both Ground- and Excited-State Photolytic Channels of NO3 → NO + O2
No Straight Path: Roaming in Both Ground- and Excited-State Photolytic Channels of NO3 → NO + O2
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Washington, DC: American Association for the Advancement of Science
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English
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Washington, DC: American Association for the Advancement of Science
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Roaming mechanisms have recently been observed in several chemical reactions alongside trajectories that pass through a traditional transition state. Here, we demonstrate that the visible light-induced reaction NO(3) → NO + O(2) proceeds exclusively by roaming. High-level ab initio calculations predict specific NO Λ doublet propensities (orientatio...
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Full title
No Straight Path: Roaming in Both Ground- and Excited-State Photolytic Channels of NO3 → NO + O2
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TN_cdi_proquest_miscellaneous_926154812
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_proquest_miscellaneous_926154812
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ISSN
0036-8075
E-ISSN
1095-9203
DOI
10.1126/science.1216911
