An Effectively Uncoupled Gd8 Cluster Formed through Fixation of Atmospheric CO2 Showing Excellent Ma...
An Effectively Uncoupled Gd8 Cluster Formed through Fixation of Atmospheric CO2 Showing Excellent Magnetocaloric Properties
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Basel: MDPI AG
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English
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Basel: MDPI AG
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The [Gd8(opch)8(CO3)4(H2O)8]·4H2O·10MeCN coordination cluster (1) crystallises in P1¯. The Gd8 core is held together by four bridging carbonates derived from atmospheric CO2 as well as the carboxyhydrazonyl oxygens of the 2-hydroxy-3-methoxybenzylidenepyrazine-2-carbohydrazide (H2opch) Schiff base ligands. The magnetic measurements show that the Gd...
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Full title
An Effectively Uncoupled Gd8 Cluster Formed through Fixation of Atmospheric CO2 Showing Excellent Magnetocaloric Properties
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TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10779177
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10779177
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ISSN
1422-0067,1661-6596
E-ISSN
1422-0067
DOI
10.3390/ijms25010264
