Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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Redox-inactive metals are found in biological and heterogeneous water oxidation catalysts, but, at present, their roles in catalysis are not well understood. Here, we report a series of high-oxidation-state tetranuclear-dioxido clusters comprising three manganese centres and a redox-inactive metal (M). Crystallographic studies show an unprecedented...
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Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
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TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3654670
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3654670
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1755-4330
E-ISSN
1755-4349
DOI
10.1038/nchem.1578
