A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
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Publisher
London: Nature Publishing Group UK
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Language
English
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Publisher
London: Nature Publishing Group UK
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Contents
Rotaxanes can display molecular chirality solely due to the mechanical bond between the axle and encircling macrocycle without the presence of covalent stereogenic units. However, the synthesis of such molecules remains challenging. We have discovered a combination of reaction partners that function as a chiral interlocking auxiliary to both orient...
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Full title
A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes
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TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7612332
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7612332
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ISSN
1755-4330
E-ISSN
1755-4349
DOI
10.1038/s41557-021-00825-9
