Ir-catalyzed enantioselective B−H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboran...
Ir-catalyzed enantioselective B−H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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The asymmetric synthesis of chiral-at-cage
o
-carboranes, whose chirality is associated with the substitution patterns on the polyhedron, is of great interest as the icosahedral carboranes have wide applications in medicinal and materials chemistry. Herein we report an intermolecular Ir-catalyzed enantioselective B−H alkenylation for efficien...
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Ir-catalyzed enantioselective B−H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes
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TN_cdi_doaj_primary_oai_doaj_org_article_22475ac96ec64e96ba3f2a85735d8cf4
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_22475ac96ec64e96ba3f2a85735d8cf4
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-021-27441-y