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Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benz...

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benz...

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_227ea8c9a6cb41788da44f1bd2c96b15

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

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Full title

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

Publisher

Basel: MDPI AG

Journal title

Crystals (Basel), 2019-06, Vol.9 (6), p.319

Language

English

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Publication information

Publisher

Basel: MDPI AG

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Scope and Contents

Contents

The ruthenium carbonyl compounds, Ru(bpy)(CO)2X2 (X = Cl, Br or I) act as neutral halogen bond (XB) acceptors when co-crystallized with 1,4-diiodotetrafluoro-benzene (DITFB). The halogen bonding strength of the Ru-X⋅⋅⋅I halogen bonds follow the nucleophilic character of the halido ligand. The strongest halogen bond occurs between the chlorido ligan...

Alternative Titles

Full title

Extended Assemblies of Ru(bpy)(CO)2X2 (X = Cl, Br, I) Molecules Linked by 1,4-Diiodotetrafluoro-Benzene (DITFB) Halogen Bond Donors

Authors, Artists and Contributors

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Primary Identifiers

Record Identifier

TN_cdi_doaj_primary_oai_doaj_org_article_227ea8c9a6cb41788da44f1bd2c96b15

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_227ea8c9a6cb41788da44f1bd2c96b15

Other Identifiers

ISSN

2073-4352

E-ISSN

2073-4352

DOI

10.3390/cryst9060319

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