Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds
Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds
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Author / Creator
Wu, Xinxin , Zhang, Hong , Tang, Nana , Wu, Zhen , Wang, Dongping , Ji, Meishan , Xu, Yan , Wang, Min and Zhu, Chen
Publisher
London: Nature Publishing Group UK
Journal title
Language
English
Formats
Publication information
Publisher
London: Nature Publishing Group UK
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Scope and Contents
Contents
Construction of C–C bonds via alkoxy radical-mediated remote C(sp
3
)–H functionalization is largely unexplored, as it is a formidable challenge to directly generate alkoxy radicals from alcohols due to the high bond dissociation energy (BDE) of O–H bonds. Disclosed herein is a practical and elusive metal-free alcohol-directed heteroarylation...
Alternative Titles
Full title
Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds
Authors, Artists and Contributors
Author / Creator
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Primary Identifiers
Record Identifier
TN_cdi_doaj_primary_oai_doaj_org_article_30bbd4ff5f03484f95eace791194e101
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_30bbd4ff5f03484f95eace791194e101
Other Identifiers
ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-018-05522-9
