Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis
Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis
About this item
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Author / Creator
Huan, Leitao , Shu, Xiaomin , Zu, Weisai , Zhong, De and Huo, Haohua
Publisher
London: Nature Publishing Group UK
Journal title
Language
English
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Publication information
Publisher
London: Nature Publishing Group UK
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Scope and Contents
Contents
Asymmetric C(sp
3
)−H functionalization is a persistent challenge in organic synthesis. Here, we report an asymmetric benzylic C−H acylation of alkylarenes employing carboxylic acids as acyl surrogates for the synthesis of α-aryl ketones via nickel and photoredox dual catalysis. This mild yet straightforward protocol transforms a diverse arra...
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Full title
Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis
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Author / Creator
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Record Identifier
TN_cdi_doaj_primary_oai_doaj_org_article_3c17fee165d643adbb5f5970a04f1828
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_3c17fee165d643adbb5f5970a04f1828
Other Identifiers
ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-021-23887-2
