Molecular rearrangement of bicyclic peroxy radicals is a key route to aerosol from aromatics
Molecular rearrangement of bicyclic peroxy radicals is a key route to aerosol from aromatics
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London: Nature Publishing Group UK
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English
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London: Nature Publishing Group UK
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The oxidation of aromatics contributes significantly to the formation of atmospheric aerosol. Using toluene as an example, we demonstrate the existence of a molecular rearrangement channel in the oxidation mechanism. Based on both flow reactor experiments and quantum chemical calculations, we show that the bicyclic peroxy radicals (BPRs) formed in...
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Molecular rearrangement of bicyclic peroxy radicals is a key route to aerosol from aromatics
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TN_cdi_doaj_primary_oai_doaj_org_article_9a922836cdd14a9581edaac19d7d6082
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_9a922836cdd14a9581edaac19d7d6082
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ISSN
2041-1723
E-ISSN
2041-1723
DOI
10.1038/s41467-023-40675-2
