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Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS

Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_df2b19608f9b4a118e21d1c2462cd7d6

Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS

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Full title

Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS

Author / Creator

Publisher

Switzerland: MDPI AG

Journal title

Metabolites, 2025-01, Vol.15 (1), p.43

Language

English

Formats

Publication information

Publisher

Switzerland: MDPI AG

More information

Scope and Contents

Contents

Charge-free gaseous molecules labeled with deuterium
H (D) atoms elute earlier than their protium-analogs
H (H) from most stationary GC phases. This effect is known as the chromatographic H/D isotope effect (
IE
) and can be calculated by dividing the retention times (
) of the protiated (
) to those of the deuterated (
) analy...

Alternative Titles

Full title

Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS

Authors, Artists and Contributors

Author / Creator

Identifiers

Primary Identifiers

Record Identifier

TN_cdi_doaj_primary_oai_doaj_org_article_df2b19608f9b4a118e21d1c2462cd7d6

Permalink

https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_df2b19608f9b4a118e21d1c2462cd7d6

Other Identifiers

ISSN

2218-1989

E-ISSN

2218-1989

DOI

10.3390/metabo15010043

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