Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS
Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS
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Publisher
Switzerland: MDPI AG
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Language
English
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Publisher
Switzerland: MDPI AG
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Contents
Charge-free gaseous molecules labeled with deuterium
H (D) atoms elute earlier than their protium-analogs
H (H) from most stationary GC phases. This effect is known as the chromatographic H/D isotope effect (
IE
) and can be calculated by dividing the retention times (
) of the protiated (
) to those of the deuterated (
) analy...
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Full title
Underlying Mechanisms of Chromatographic H/D, H/F, cis/trans and Isomerism Effects in GC-MS
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TN_cdi_doaj_primary_oai_doaj_org_article_df2b19608f9b4a118e21d1c2462cd7d6
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https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_doaj_primary_oai_doaj_org_article_df2b19608f9b4a118e21d1c2462cd7d6
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ISSN
2218-1989
E-ISSN
2218-1989
DOI
10.3390/metabo15010043