Enols Are Common Intermediates in Hydrocarbon Oxidation
Enols Are Common Intermediates in Hydrocarbon Oxidation
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Author / Creator
Cornell Univ., Ithaca, NY (United States) , Taatjes, Craig A , Hansen, Nils , McIlroy, Andrew , Miller, James A , Senosiain, Juan P , Klippenstein, Stephen J , Qi, Fei , Sheng, Liusi , Zhang, Yunwu , Cool, Terrill A , Wang, Juan , Westmoreland, Phillip R , Law, Matthew E , Kasper, Tina and Kohse-Höinghaus, Katharina
Publisher
Washington, DC: American Association for the Advancement of Science
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English
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Washington, DC: American Association for the Advancement of Science
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Contents
Models for chemical mechanisms of hydrocarbon oxidation rely on spectrometric identification of molecular structures in flames. Carbonyl (keto) compounds are well-established combustion intermediates. However, their less-stable enol tautomers, bearing OH groups adjacent to carbon-carbon double bonds, are not included in standard models. We observed...
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Full title
Enols Are Common Intermediates in Hydrocarbon Oxidation
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TN_cdi_osti_scitechconnect_1062551
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_osti_scitechconnect_1062551
Other Identifiers
ISSN
0036-8075
E-ISSN
1095-9203
DOI
10.1126/science.1112532
