Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated i...
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
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Author / Creator
Univ. of Minnesota, Minneapolis, MN (United States) , Xiao, Dianne J. , Bloch, Eric D. , Mason, Jarad A. , Queen, Wendy L. , Hudson, Matthew R. , Planas, Nora , Borycz, Joshua , Dzubak, Allison L. , Verma, Pragya , Lee, Kyuho , Bonino, Francesca , Crocellà, Valentina , Yano, Junko , Bordiga, Silvia , Truhlar, Donald G. , Gagliardi, Laura , Brown, Craig M. and Long, Jeffrey R.
Publisher
London: Nature Publishing Group UK
Journal title
Language
English
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Publication information
Publisher
London: Nature Publishing Group UK
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Scope and Contents
Contents
Enzymatic haem and non-haem high-valent iron–oxo species are known to activate strong C–H bonds, yet duplicating this reactivity in a synthetic system remains a formidable challenge. Although instability of the terminal iron–oxo moiety is perhaps the foremost obstacle, steric and electronic factors also limit the activity of previously reported mon...
Alternative Titles
Full title
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites
Authors, Artists and Contributors
Author / Creator
Xiao, Dianne J.
Bloch, Eric D.
Mason, Jarad A.
Queen, Wendy L.
Hudson, Matthew R.
Planas, Nora
Borycz, Joshua
Dzubak, Allison L.
Verma, Pragya
Lee, Kyuho
Bonino, Francesca
Crocellà, Valentina
Yano, Junko
Bordiga, Silvia
Truhlar, Donald G.
Gagliardi, Laura
Brown, Craig M.
Long, Jeffrey R.
Identifiers
Primary Identifiers
Record Identifier
TN_cdi_osti_scitechconnect_1458980
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_osti_scitechconnect_1458980
Other Identifiers
ISSN
1755-4330
E-ISSN
1755-4349
DOI
10.1038/nchem.1956
