Compression of curium pyrrolidine-dithiocarbamate enhances covalency
Compression of curium pyrrolidine-dithiocarbamate enhances covalency
About this item
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Author / Creator
Florida State Univ., Tallahassee, FL (United States) , Sperling, Joseph M. , Warzecha, Evan J. , Celis-Barros, Cristian , Sergentu, Dumitru-Claudiu , Wang, Xiaoyu , Klamm, Bonnie E. , Windorff, Cory J. , Gaiser, Alyssa N. , White, Frankie D. , Beery, Drake A. , Chemey, Alexander T. , Whitefoot, Megan A. , Long, Brian N. , Hanson, Kenneth , Kögerler, Paul , Speldrich, Manfred , Zurek, Eva , Autschbach, Jochen and Albrecht-Schönzart, Thomas E.
Publisher
London: Nature Publishing Group UK
Journal title
Language
English
Formats
Publication information
Publisher
London: Nature Publishing Group UK
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More information
Scope and Contents
Contents
Curium is unique in the actinide series because its half-filled 5
f
7
shell has lower energy than other 5
f
n
configurations, rendering it both redox-inactive and resistant to forming chemical bonds that engage the 5
f
shell
1
–
3
. This is even more pronounced in gadolinium, curium’s lanthanide analogue, owing...
Alternative Titles
Full title
Compression of curium pyrrolidine-dithiocarbamate enhances covalency
Authors, Artists and Contributors
Author / Creator
Sperling, Joseph M.
Warzecha, Evan J.
Celis-Barros, Cristian
Sergentu, Dumitru-Claudiu
Wang, Xiaoyu
Klamm, Bonnie E.
Windorff, Cory J.
Gaiser, Alyssa N.
White, Frankie D.
Beery, Drake A.
Chemey, Alexander T.
Whitefoot, Megan A.
Long, Brian N.
Hanson, Kenneth
Kögerler, Paul
Speldrich, Manfred
Zurek, Eva
Autschbach, Jochen
Albrecht-Schönzart, Thomas E.
Identifiers
Primary Identifiers
Record Identifier
TN_cdi_osti_scitechconnect_2370431
Permalink
https://devfeature-collection.sl.nsw.gov.au/record/TN_cdi_osti_scitechconnect_2370431
Other Identifiers
ISSN
0028-0836
E-ISSN
1476-4687
DOI
10.1038/s41586-020-2479-2
